Template-Dependent Photochemical Reactivity of Molecular Metal Oxides

Johannes Tucher, Katrin Peuntinger, Johannes T. Margraf, Timothy Clark, Dirk M. Guldi, Carsten Streb
2015 Chemistry - A European Journal  
A combined experimental and theoretical study shows that the photooxidative activity of two isostructural metal oxide clusters depends on their internal templates. To this end, two halide-templated bismuth vanadium oxide clusters [X(Bi(dmso)3)2V12O33] -(X = Cl -, Br - [a]
doi:10.1002/chem.201501129 pmid:25907798 fatcat:mdseobsorzazze3f4uvv7ucj5a