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A combined experimental and theoretical study shows that the photooxidative activity of two isostructural metal oxide clusters depends on their internal templates. To this end, two halide-templated bismuth vanadium oxide clusters [X(Bi(dmso)3)2V12O33] -(X = Cl -, Br - [a]doi:10.1002/chem.201501129 pmid:25907798 fatcat:mdseobsorzazze3f4uvv7ucj5a