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Using a neon discharge as a well-assessed reference, we demonstrate the validation of atomic data for discharge modeling with data from emission spectroscopy. Specifically, a collisional radiative model of a neon dc discharge was set up using a set of structure and collision data from a semirelativistic B-spline R-matrix calculation by Zatsarinny and Bartschat (2004 J. Phys. B: At. Mol. Opt. Phys. 37 2173) and the electron-energy distribution function of the plasma was determined from thedoi:10.1088/1367-2630/12/7/073018 fatcat:6kz4adzndrdjjas5zxoyovbfnq