A simple route to azaborinylphosphines: isoelectronic B–N analogues of arylphosphine ligands

Jonathan A. Bailey, Mairi F. Haddow, Paul G. Pringle
2014 Chemical Communications  
Azaborinylphosphines are readily prepared by the reaction of silylphosphines with a chloroborane under mild conditions; they are shown to contain P–B bonds that are sufficiently robust to allow these ligands to be used in homogeneous catalysis.
doi:10.1039/c3cc49000a pmid:24345849 fatcat:i4dcjuzn7nfiri3ci4quaj6mie