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Work supported under DE-FG02-00ER15108 resulted in much new insight into unusual mechanisms of metalloenzymes involved in anaerobic metabolism in methanogens, other archaea, and bacteria, and was published in a series of high quality publications supported by funding which spanned from 2000 to around 2009. The extensive results from these efforts are briefly summarized for each of the major publications as follows.doi:10.2172/1097089 fatcat:wx6g6qeipngznnwrkntaj7rhbq