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Synthesis and Styrene Copolymerization of Novel Trisubstituted Ethylenes: 3. Phenoxy Ring-substituted 2-Methoxyethyl Phenylcyanoacrylates [post]

William S. Schjerven, Kacy S. Bradford, Abeer Fatima, Muhammed M. Ghazal, Ljupka Gjorgjevska, Stephen J. Heimann, Alexis B. Jordan, Erick Ortega, Francis C. Regacho, Anna M. Rohrer, Karla A. Santana, Caitlin Smicklas (+5 others)
2020 unpublished

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<p>Novel trisubstituted ethylenes, alkyl ring-substituted 2-methoxyethyl phenylcyanoacrylates, RPhCH=C(CN)CO<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>OCH<sub>3</sub><sub> </sub>(where R is 3-phenoxy, 3-(4-chlorophenoxy), 4-(4-chlorophenoxy), 2-(4-fluorophenoxy), 4-(4-fluorophenoxy), 2-(3-methoxyphenoxy), 2-(4-methoxyphenoxy), 3-(4-methoxyphenoxy), 4-(4-methoxyphenoxy), 3-(4-methylphenoxy), 4-(4-methylphenoxy), 3-(3,5-dichlorophenoxy), 4-(2,4-dichlorophenoxy), 3-(3-trifluoromethyl)phenoxy) were
more » ... pared and copolymerized with styrene. The ethylenes were synthesized by the piperidine catalyzed Knoevenagel condensation of ring-substituted benzaldehydes and 2-methoxyethyl cyanoacetate, and characterized by CHN analysis, IR, <sup>1</sup>H and <sup>13</sup>C NMR. All the ethylenes were copolymerized with styrene in solution with radical initiation (ABCN) at 70°C. The compositions of the copolymers were calculated from nitrogen analysis.</p>
doi:10.26434/chemrxiv.13262660.v3 fatcat:tl4vzjdayran7m3japia3y3of4
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William S. Schjerven, Kacy S. Bradford, Abeer Fatima, Muhammed M. Ghazal, Ljupka Gjorgjevska, Stephen J. Heimann, Alexis B. Jordan, Erick Ortega, Francis C. Regacho, Anna M. Rohrer, Karla A. Santana, Caitlin Smicklas, Isabel Uribe, Yazmeen I. Villanueva, Jin Ju Yi, Sara M. Rocus, Gregory Kharas. "Synthesis and Styrene Copolymerization of Novel Trisubstituted Ethylenes: 3. Phenoxy Ring-substituted 2-Methoxyethyl Phenylcyanoacrylates." (2020)