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Zur Reaktion aromatischer Phosphanderivate mit Elektronen, I. / On the Reaction of Aromatic Phosphane Derivatives with Electrons, I
1981
Zeitschrift für Naturforschung. B, A journal of chemical sciences
Preserved Fulltext
The compounds ;p-Me2P(X)-C6H4-P(X)Me2, X = O, S, Se, NPh undergo one-electron reduction at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixture. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2P-C6H4-PMe2 · with the coordinated groups X.
doi:10.1515/znb-1981-0207
fatcat:v7j6f3l4ubh63edoocf4sca4vi