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Complexes of the general composition RhIII(phpy)2(S∪E) with phpy− = 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E− = diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescence which originates from a phpy ππ∗ intraligand triplet. For the complex with S∪E− = 2-quinolinethiolate (or thiooxinate) the lowest-energy excited state is of the quinolinethiolate intraliganddoi:10.1515/znb-2005-0323 fatcat:iamewrq5xjcg3ilsmplelh3zty