Phosphor coated NiO-based planar inverted organometallic halide perovskite solar cells with enhanced efficiency and stability

Jin Cui, Pengfei Li, Zhifan Chen, Kun Cao, Dan Li, Junbo Han, Yan Shen, Mingying Peng, Yong Qing Fu, Mingkui Wang
2016 Applied Physics Letters  
This work investigates non-rare-earth phosphor (Sr 4 Al 14 O 25 :Mn 4+ , 0.5%Mg) with intensively red luminescence as a luminescent down-shifting layer for perovskite solar cells. The power conversion efficiency of the fabricated device with a structure of NiO/CH 3 NH 3 PbI 3 /[6,6]-phenyl C 61 -butyric acid methyl ester/Au coated with phosphor layer shows a 10% increase as compared with that of the control devices. Importantly, the phosphor layer coating can realize UV-protection as well as
more » ... erproof capability, achieving a reduced moisture-degradation of CH 3 NH 3 PbI 3 perovskite upon applying an UV irradiation. Therefore, perovskite devices using this luminescent coating show a combined enhancement in both UV downshifting conversion and long term stability. This can be expanded as a promising encapsulation technique in the perovskite solar cell community. A significant progress has been achieved over the past few years for the development of solar cells using hybrid lead halide perovskite as next generation light harvester. 1-4 Currently, the certified power conversion efficiency (PCE) for the perovskite solar cells is dramatically increased over 22.1% for the lab-scale devices. 5 In addition to the high PCE, the perovskite solar cells take advantages of low cost and solution processability, making them as a promising photovoltaic technology till date. 6,7 At present, excellent solar cell performance has been achieved for devices based on inorganic-organic hybrid lead perovskites. However, a number of obstacles limit its commercialization, including long-term device stability in operation conditions with oxygen, humidity/rain/ice, heat, and ultra-violet (UV) light exposure. Previous works have pointed
doi:10.1063/1.4965838 fatcat:pbq5w5tnznba5jflspvyb34ih4