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Invention of organotellurium and organostibine mediators for highly controlled degenerative transfer polymerization
Proceedings of the Japan Academy. Series B, Physical and biological sciences
Polymer-end mimetic organotellurium and organostibine compounds mediate highly controlled living radical polymerizations that allow the molecular weight to be controlled accurately and give well-defined end-groups. A variety of both conjugated (including styrene, acrylate and methacrylate derivatives) and unconjugated monomers (including 1-vinyl-2-pyrrolidinone and vinyl acetate) have been successfully polymerized in a controlled manner. The higher controllability of organotellurium-anddoi:10.2183/pjab.81.117 fatcat:fzoc5zml5bbn7iupfuifx32dtm