Formation mechanisms of macroscopic globules in andesitic glasses from the Izu–Bonin–Mariana forearc (IODP Expedition 352) [article]

Raul O.C. Fonseca, Lina T. Michely, Maria Kirchenbaur, Julie Prytulak, Jeffrey Ryan, Kerstin Hauke, Felipe P. Leitzke, Renat R. Almeev, Chris S. Marien, Axel Gerdes, Rico Schellhorn, University, My
2021
The Izu–Bonin–Mariana volcanic arc is situated at a convergent plate margin where subduction initiation triggered the formation of MORB-like forearc basalts as a result of decompression melting and near-trench spreading. International Ocean Discovery Program (IODP) Expedition 352 recovered samples within the forearc basalt stratigraphy that contained unusual macroscopic globular textures hosted in andesitic glass (Unit 6, Hole 1440B). It is unclear how these andesites, which are unique in a
more » ... tigraphic sequence dominated by forearc basalts, and the globular textures therein may have formed. Here, we present detailed textural evidence, major and trace element analysis, as well as B and Sr isotope compositions, to investigate the genesis of these globular andesites. Samples consist of K 2O -rich basaltic globules set in a glassy groundmass of andesitic composition. Between these two textural domains a likely hydrated interface of devitrified glass occurs, which, based on textural evidence, seems to be genetically linked to the formation of the globules. The andesitic groundmass is Cl rich (ca. 3000µg/g), whereas globules and the interface are Cl poor (ca. 300µg/g). Concentrations of fluid-mobile trace elements also appear to be fractionated in that globules and show enrichments in B, K, Rb, Cs, and Tl, but not in Ba and W relative to the andesitic groundmass, whereas the interface shows depletions in the latter, but is enriched in the former. Interestingly, globules and andesitic groundmass have identical Sr isotopic composition within analytical uncertainty (87Sr / 86Sr of 0.70580 ± 10), indicating that they likely formed from the same source. However, globules show high d11B (ca. + 7 [0/00]), whereas their host andesites are isotopically lighter (ca. – 1 [0/00]), potentially indicating that whatever process led to their formation either introduced heavier B isotopes to the globules, or induced stable isotope fractionation of B between globules and their groundmass. Based on the bulk of the textural information [...]
doi:10.15488/10672 fatcat:hfcw2o5yijcdrb7goff3qz5l34