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Van der Waals–London interaction of atoms with pseudo-relativistic kinetic energy
[report]
2022
We consider a multiatomic system where the nuclei are assumed to be point charges at fixed positions. Particles interact via Coulomb potential and electrons have pseudo–relativistic kinetic energy. We prove the van der Waals-London law, which states that the interaction energy between neutral atoms decays as the sixth power of the distance $|D|$ between the atoms. In the many atom case, we rigorously compute all the terms in the binding energy up to the order $|D|^{−9}$ with error term of order
doi:10.5445/ir/1000150351
fatcat:ma77p55c25gjzbtyc5ptcaufim