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Solvent-free autocatalytic supramolecular polymerization
Solvent-free chemical manufacturing is one of the awaited technologies for addressing an emergent issue of serious environmental pollution. Here, we report "solvent-free autocatalytic supramolecular polymerization (SF-ASP)", where a phthalonitrile derivative with hydrogen-bonding side chains as the monomer is autocatalytically transformed into the corresponding phthalocyanine in an exceptionally high yield (> 80%). The target phthalocyanine, if any is produced, nucleates and initiatesdoi:10.21203/rs.3.rs-136295/v1 fatcat:p45fqs7pijgirmnu5noslgqc7m