Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH2 (L = HC(MeCNDipp)2, Dipp = 2,6-diisopropylphenyl)

Lauren K. Keyes, Angela D. K. Todd, Nick A. Giffin, Alex J. Veinot, Arthur D. Hendsbee, Katherine N. Robertson, Stephen J. Geier, Jason D. Masuda
2017 RSC Advances  
A bulky aluminum dihydride reacts with R–OH and organocarbonyls to give a variety of products; including OC insertion into the Al–H bond.
doi:10.1039/c7ra06526d fatcat:zpkiba4uwbf5tlartuezegu3km