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Mode-specific intermolecular vibrational energy transfer. II. Deuterated water and potassium selenocyanate mixture
Journal of Chemical Physics
Vibrational energy transfer from the first excited state ͑2635 cm −1 ͒ of the O-D stretch of deuterated water ͑D 2 O͒ to the 0-1 transition ͑2075 cm −1 ͒ of the CN stretch of potassium selenocyanate ͑KSeCN͒ in their 2.5:1 liquid mixture was observed with a multiple-mode two dimensional infrared spectroscopic technique. Despite the big energy mismatch ͑560 cm −1 ͒ between the two modes, the transfer is still very efficient with a time constant of 20 ps. The efficient energy transfer is probablydoi:10.1063/1.3458825 pmid:20649335 fatcat:g3jlp56rpvdmxbybctpdo4duui