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Tripodal Ru(II) complexes with conjugated and non-conjugated rigid-rod bridges for semiconductor nanoparticles sensitization
2004
Tetrahedron
Three tripodal Ru(II)-polypyridyl complexes have been synthesized as models to study long-range electron transfer in TiO 2 semiconductor nanoparticles thin films, in particular to study the effect of the conjugation of the bridge containing the Ru complex and for distance dependence studies. The tripodal sensitizers, which are 1,3,5,7-tetraphenyladamantane derivatives having three COOMe anchoring groups and one rigid-rod bridge substituted with a Ru(II) complex, are the longest prepared to date
doi:10.1016/j.tet.2004.06.124
fatcat:ik2nmiqcszgj3g2uwh6g3bvxbq