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Oxidation of Hydroxylamine by Waugh Type POM, Enneamolybdomanganate(IV) ion (A Kinetic and Mechanistic Study)
2017
Oriental Journal of Chemistry
ABSTARCT The reaction between hydroxyl amine and Waugh-type polyoxometalate, enneamolybdomanganate(ΙV), was investigated under pseudo-first-order condition in aqueous perchloric acid. The product of the reaction was nitrous oxide as determined by studying the stoichiometry which requires one mol of oxidant per mole of hydroxylamine. The rate of reaction increases as hydrogen ion and oxidant, enneamolybdomanganate(ΙV), concentrations increase, while it remains unchanged as the hydroxylamine
doi:10.13005/ojc/330554
fatcat:m27vvflelzerhbefx7pkjj4g3m