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Asymmetric synthesis of chiral-at-metal complexes with pentadentate bis(oxazoline) ligands
2005
A number of novel chiral, pentadentate bis(oxazoline)-pyridine-ligands and the corresponding metal complexes were synthesized. Especially the mononuclear complexes of late transition metals (Mn-Zn) were analyzed with respect to their structures in the solid and the solution state by e.g. NMR-, UV- and CD-spectroscopy. Complex formation proved to be highly diastereoselective in almost every case with regard to the configuration at the stereogenic metal center. A number of coordination geometries
doi:10.5283/epub.10273
fatcat:wvyvl6cyqfcj5niz3bpx7deplm