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Experimental and theoretical x-ray transition energies are precisely estimated and compared for 40<2<100. All allowed and forbidden intervals for the n=l to n=2, 3 levels are determined. The experimental values are derived from absolute wavelength measurements of Ka and KB transitions and from L series x-ray measurements. The theoretical values are obtained using a multiconfiguration Dirac-Fock code with some modifications in the Lamb shift calculations. Comparison between experiment and theorydoi:10.1051/jphyscol:1987997 fatcat:2tv7hhghyvbc5ignfpkmh4d6cy