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Visualization of the effective potential and Coulomb correlations in finite metallic systems
2002
Physical Chemistry, Chemical Physics - PCCP
We present an analytic ansatz to find the effective electrostatic potential and Coulomb correlations in multicenter problems, specifically homogeneous and doped clusters of metal atoms. The approach is based on a quasi-classical density-functional treatment. We focus on the interpretive aspect of our findings, particularly on extracting insight regarding the geometric effects of Coulomb correlations for any given spatial disposition of ionic cores. For singly-doped metallic clusters we obtain a
doi:10.1039/b111394c
fatcat:qnaac4z6s5ahxncoglhjhfhi6u