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In this paper, we propose a strategic molecular design of closo-o-carborane-based donor‒acceptor dyad system that exhibits thermally activated delayed fluorescence (TADF) in solution state at ambient temperature. Planar 9,9-dimethyl-9H-fluorene-based compounds...doi:10.1039/d1sc00791b fatcat:32hfnehoajcelp2vkgxjvoev4y