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13C NMR Studies on Photoinitiated Crosslinks of LDPE Model Compounds
1996
Journal of Photopolymer Science and Technology (Fotoporima Konwakai shi)
H-and Y-type crosslinks formed in the benzophenone-photoinitiated crosslinking of various model compounds of low-density polyethylene (LDPE) have been observed and identified for the first time by 13C NMR spectroscopy. The quantitative studies show that both H-and Y-links are formed during the photo crosslinking of dodecane and their concentrations are almost the same; the yield of H-links in the crosslinked isooctane is slightly greater than that of Y-links; in contrast, Y-links are dominant
doi:10.2494/photopolymer.9.157
fatcat:bghmuxrenraldgpxeuoxtkt3zy