Synthesis and Charaterisation of Metal chelates of (5-(2,3-dimethyl-1- phenyl-3-pyrazolin-5-one-4-ylazo)-1H-pyrimidine-2,4-dione)

2018 Journal of Ultra Chemistry  
An azo dye UAAP and Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)complexes were synthesized and characterized using elemental analysis, mass spectra, UV-Vis, fluorescence spectra, ESR spectrum, IR spectra, NMR spectra, NLO property, molar conductance and magnetic measurements. The spectral and analytical data reveal that UAAP act as both bidentate and tridentate ligand. The molar conductance data reveal that complexes Co(II), Cu(II) and Zn(II) are nonelectrolytic and Mn(II), Ni(II) 1:2 electrolyte
more » ... n nature. Based on all data structures were proposed for UAAP and complexes. The UAAP and metal complexes were screened for antimicrobial activity, antioxidant study, DNA cleavage analysis and anticancerous investigation.
doi:10.22147/juc/140202 fatcat:f6ppxpiw5bhbthwi7my4j32bdy