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Contributions to the Chemistry of Boron, 204 [1] An Unusual [2+2]-Cycloaddition Reaction of Dicobalt Octacarbonyl
1990
Zeitschrift für Naturforschung. B, A journal of chemical sciences
Preserved Fulltext
Dicobalt octacarbonyl reacts with (9-fluorenylidene)(2,2,6,6-tetramethylpiperidino)borane (1) at ambient conditions in an unexpected [2+2]-cycloaddition to yield an oxaboretane derivative (2). The structure of 2 has been determined by X-ray diffraction analysis. Similarities between the complex 2 and other oxaboretanes are discussed.
doi:10.1515/znb-1990-0614
fatcat:q4m3lbj6cbf2bo7cwxx7roahdi