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Conformational effects on melting of methoxymethylated nylon-6
1988
Sen'i Gakkaishi
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A thermodynamic consideration of the coefficient a in the modified Flory's equation (1) for the melting of random copolymers and the transition free energy (fx,) of quasi-crystals in the amorphous regions led to an equilibrium equation of FA = FB. FA and FB are the total interaction free energies per molar structural unit of major and minor components A and B in a copolymer, respec tively. By using this equation, the conformation dependence of the intermolecular interaction free energy was
doi:10.2115/fiber.44.4_186
fatcat:eymhwzysxngnffy77idjnosy7m