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Effect of Metal Dispersion on the Hydrogenation of 2-Amyl Anthraquinone over Pd/Al2O3Catalyst
2016
Journal of the Brazilian Chemical Society
A series of highly dispersed Pd/Al 2 O 3 catalysts were prepared via the polyol method. The catalysts were characterized by nitrogen adsorption, X-ray diffraction (XRD), UV-Vis spectrophotometry, temperature programmed reduction (TPR) and transmission electron microscopy (TEM). The influence of Pd particle size on the hydrogenation of 2-amyl anthraquinone (AAQ) was investigated in a trickle-bed reactor. The turnover frequency (TOF) showed antipathetic size dependence while the space time yield
doi:10.5935/0103-5053.20160001
fatcat:igngvpvavzayzlhv6hsewhnjfy