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Journal of Chemical and Pharmaceutical Research
Kinetic investigation on oxidation of some Cyclanols (Cyclopropanol, Cyclobutanol, Cyclopentanol, Cyclohexanol and Cycloheptanol) by 1-chlorobenzimidazole (CBI) has been studied in 80% acetic acid-water (v/v) medium. The reaction exhibits first order rate dependence each with respect to [CBI], [Cyclanols] and [H + ]. The increase in dielectric constant of the medium increases the rate of the reaction. The variation of ionic strength has no significant effect on the reaction rate. The reactionfatcat:tvjwg65hfraq3avwcjbatrkqcq