Physicochemical Implications of Surface Alkylation of High-valent, Lindqvist-type Polyoxovanadate-alkoxide Clusters

Alex A Fertig, S M Gulam Rabbani, Melissa D. Koch, William W. Brennessel, Pere Miro Ramirez, Ellen Matson
2021 Nanoscale  
We report a rare example of the direct alkylation of the surface of a plenary polyoxometalate cluster by leveraging the increased nucleophilicity of vanadium oxide assemblies. Addition of methyl trifluoromethylsulfonate...
doi:10.1039/d0nr09201k pmid:33734254 fatcat:krxskht2czhcfertgzkrvf7cre