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Crystal face dependence of the decomposition activity of MnO x -modified rutile-type TiO 2 on 2-naphthol in water in the dark was investigated. Clusters of MnO x were modified onto (110) and (001) surfaces of rutile single crystals using chemisorption calcination cycle (CCC) processing. The major valences of Mn on (110) were Mn(III) and Mn(IV), whereas those on (001) were Mn(II) and Mn(III). Energy calculations for the MnO x cluster on (110) corresponded to experimentally obtained results.doi:10.2109/jcersj2.18066 fatcat:snkrjrasondtrc2ug6crg5zcu4