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Axial Preferences in Allylation Reactions via the Zimmerman–Traxler Transition State
2013
Accounts of Chemical Research
CONSPECTUS The reaction of substituted allylmetal on prostereogenic carbonyl compound can give rise to up to two racemic diastereomers (syn and anti). Classically, when anti selectivity was observed from pure E-isomers while the Z-isomers exhibit syn-selectivity, the empirical Zimmerman -Traxler
doi:10.1021/ar4000532
pmid:23672428
pmcid:PMC3714348
fatcat:kjidm5ibgjb4vlv3flpqubcl2a