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One experimental strategy to prepare a nitrosyl metal complex is based on the acid-base conversion of NO 2 into NO + . Here, we employed UV-vis absorption and FTIR spectroscopies to investigate the reaction of cis-[Ru(NO 2 )(bpy) 2 (imN)]PF 6 with H 3 O + , which produced cis-[Ru(NO)(bpy) 2 (imN)](PF 6 ) 3 complex. Chromatographic studies were carried out and showed that immediately after nitrite complex was dissolved only one species was present with retention time(t R ) of 6.81 minutes.doi:10.21577/0100-4042.20170181 fatcat:77dvbdrsprdzvgflxddtaq6bce