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This work aims to study the effects of urea, glycerol and their mixture as plasticizers for cassava starch films, regarding their impact on the material structure, water susceptibility, barrier and mechanical properties. All plasticizers were compatible with starchbased matrices, without detecting migration at the plasticizers level tested. In general water related properties were not affected. Plasticizer-polymer interactions as well as those involving water molecules were evidenced bydoi:10.22161/ijeab/3.5.38 fatcat:5c4gmve7ova7tlygjqmtnek77u