Indium(iii) catalysed substrate selective hydrothiolation of terminal alkynes

Rupam Sarma, Nimmakuri Rajesh, Dipak Prajapati
2012 Chemical Communications  
All the commercially available regents were used as received. IR spectra were recorded on a SHIMADZU FTIR-8400. NMR spectra were recorded on Advance DPX 300 MHz FT-NMR spectrometer using tetramethylsilane (TMS) as an internal standard. Mass spectra were recorded on ESQUIRE 3000 Mass spectrometer. All experiments were monitored by thin layer chromatography (TLC). TLC was performed on pre-coated silica gel plates (Merck). After elution, plate was visualized under UV illumination at 254 nm for UV
more » ... ctive materials. Further visualization was achieved by staining KMnO 4 and warming in a hot air oven. Column chromatography was performed on silica gel (100-200 mesh, Merck) using ethyl acetate: hexane as eluent.
doi:10.1039/c2cc30350g pmid:22421681 fatcat:4xwu5zwhunhlhc4g4r3gsf6oie