Internal asymmetric induction by the C-6 substituent on the oxidation reaction of interglycosidic sulfur atom of thiodisaccharides

J. P. Colomer, A. B. Peñéñory, O. Varela
2017 RSC Advances  
Complete diastereoselectivity was archived in the oxidation of 3-deoxy-S-(1-4)-disaccharides due to anchimeric assistance of the terminal CH2OH group.
doi:10.1039/c7ra07225b fatcat:7f5igoc5pbhbnexvf2jbou6ula