Valence band splitting in bulk dilute bismides
Lars C. Bannow, Stefan C. Badescu, Jörg Hader, Jerome V. Moloney, Stephan W. Koch
2017
Applied Physics Letters
The electronic structure of bulk GaAs_1-xBi_x systems for different atomic configurations and Bi concentrations is calculated using density functional theory. The results show a Bi-induced splitting between the light-hole and heavy-hole bands at the Γ-point. We find a good agreement between our calculated splittings and experimental data. The magnitude of the splitting strongly depends on the local arrangement of the Bi atoms but not on the uni-directional lattice constant of the supercell. The
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... additional influence of external strain due to epitaxial growth on GaAs substrates is studied by fixing the in-plane lattice constants.
doi:10.1063/1.5005156
fatcat:u2cirsi2q5dqllcqbpmi3j62tm