[Bis(diphenylphosphanyl)dimethylsilane κ2P,P′] tetracarbonylchromium(0) [article]

N. Peulecke, S. Peitz, B.H. Müller, A. Spannenberg, U. Rosenthal, University, My
2020
The title compound, [Cr(C26H26P2Si)(CO) 4], was obtained by the reaction of Ph2PSiMe 2PPh2 with Cr(CO)6 in refluxing toluene by ligand exchange. The CrC4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 80.27 (1)°.
doi:10.34657/4048 fatcat:gmgnza35grallloqgrnqkhl5xa