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Flavoenzyme‐mediated regioselective aromatic hydroxylation with coenzyme biomimetics
2019
ChemCatChem
Regioselective aromatic hydroxylation is desirable for the production of valuable compounds. External flavin-containing monooxygenases activate and selectively incorporate an oxygen atom in phenolic compounds through flavin reduction by the nicotinamide adenine dinucleotide coenzyme, and subsequent reaction with molecular oxygen. This study provides the proof of principle of flavoenzyme-catalyzed selective aromatic hydroxylation with coenzyme biomimetics. The carbamoylmethyl-substituted
doi:10.1002/cctc.201902044
fatcat:killlck54nhhbchl5jtg4iqcju