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A synthetic route to a pyranose derived epoxy-exo-glycal has been developed from D-glucose. An attempted, one-pot bromination-elimination-oxirane formation, protocol that had worked well on furanoses, resulted only in the generation of 2-bromo-C-1-methyl pyranoid glycals.doi:10.3998/ark.5550190.0012.304 fatcat:uw7nersfivalrmqazuvnpvacoa