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The complexes of cobalt(ll) halides and cobalt(ll) thiocyanate with several aromatic amines have been prepared. The stereochemistry of the metal in each complex in the solid-state has been assigned. These assignments have been made using evidence from absorption spectra, magnetic moments, infra-red spectra and thermogravimetric analysis (in one instance). The complexes of the halides are all tetrahedral monomers while those of the thiocyanate are octahedral polymers. Ethanol and water adductsdoi:10.26190/unsworks/10618 fatcat:ph3lkdnfzfeingl4o4cyunpxny