Ionic liquids - deanol derivatives as the Diels-Alder reaction solvents

Ewa Janus, Anna Syguda, Katarzyna Materna
2010 Open Chemistry  
AbstractThe Diels-Alder reaction between cyclopentadiene and dienophiles in deanol derivatives containing bis(trifluoromethylsulfonyl)imide anion as media have been studied. The effect of the substituents attached to the cation on the endo:exo selectivity as well as the reaction yield have been evaluated in the absence and presence of Lewis acid catalyst - Y(OTf)3. Catalytic activity of metal triflates and the recycling of chosen catalytic systems have also been investigated
doi:10.2478/s11532-010-0092-1 fatcat:srwzszn2bfe33o3o6x2skrs4v4