Control of Generation of Lead Sulfate Particles in Lead-acid Battery using Ion-exchangeable Glass Mat as Separator

Kenji Iimura, Shuto Osumi, Kouji Maeda, Kyoko Hirai, Hiroshi Satone
2020 Journal of the Society of Powder Technology Japan  
Ion exchangeable inorganic fibers based on sodium silicate have been successfully developed. The fibers have the ion exchange capacity of 83.8 meq·100 g −1 which is comparable to that of ion-exchangeable resin. Absorbing glass mat (AGM) for separators in lead-acid batteries was also successfully prepared with ion-exchangeable sodium silicate fibers. It was clarified by charge/discharge cycle test and morphological observation with scanning electron microscopy that the ion exchangeable AGM can
more » ... hibit the precipitation of PbSO 4 particles on the surface of electrodes and consequently reduces the deterioration in coulomb efficiency during repetitive cycles. Furthermore it was also clarified that ion-exchangeable AGM can inhibit the precipitation of PbSO 4 in separator itself notably. This will allow the reduction of thickness of separator and downsizing of lead battery body.
doi:10.4164/sptj.57.144 fatcat:kkfo6z3pkjegdhkom32jsq6cbi