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CH3CH2OD/D2O binary condensation in a supersonic Laval nozzle: Presence of small clusters inferred from a macroscopic energy balance
Journal of Chemical Physics
We determined the heat released in the condensing flow of a CH 3 CH 2 OD/ D 2 O/carrier gas mixture ͑EtOD/ D 2 O for brevity͒ through a supersonic Laval nozzle by integrating the equations for supersonic flow with condensation, using the static pressure, temperature, and mole fractions of EtOD and D 2 O monomers ͓S. Tanimura, B. E. Wyslouzil, M. S. Zahniser, et al., J. Chem. Phys. 127, 034305 ͑2007͔͒ as inputs. By considering the depletion of the monomer species, the deviation of the pressuredoi:10.1063/1.3360304 pmid:20405990 fatcat:iflnxwzwwza4lbwsb5u3outxnq