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Analytic example of a free energy functional
2000
Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics
We use the ideas of Percus for the construction of classical density functionals for two model interactions: simple hard spheres and adhesive hard spheres ͑AHSs͒. The required input, the properties of the uniform fluid, is taken from the analytic mean spherical solution for these two systems. For hard spheres we derive-via a bilinear decomposition of the direct correlation functions-a set of basis functions, which is the same as the one presented by Rosenfeld in his fundamental measure theory
doi:10.1103/physreve.62.3640
pmid:11088864
fatcat:d7ac5juqtfgivnhhiriy6x2oby