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Reactions of ceric ammonium nitrate: I. with substituted cycloheptatrienes, II. with diazoalkanes, III. with sodium azide and olefins
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and a-azido-jS-nitratoalkanes are isolated in high yields. This may be the first example in which the azido radical is trapped in the cerlum(iv) oxidation of azide ion. Further more the products may prove to have interesting physiological properties.
doi:10.31274/rtd-180813-2661
fatcat:vd6suwmbtncxjosdmy2uw3wmji