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A new variant of a scaling hypothesis and a fundamental equation of state based on it

I V Kudryavtseva, V A Rykov, S V Rykov, E E Ustyuzhanin
2018 Journal of Physics, Conference Series  

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This paper deals with a fundamental equation of state (FEOS) for substances. We have suggested a new method. It allows constructing FEOS that is based on the scaling theory of critical phenomena and describes thermodynamic properties related to liquid and gas phases of a substance in a wide range of the pressures and temperatures. In the framework of the methodological approach, we have provided: (i) a transition of FEOS in a virial equation of state in the low density region; (ii) a transition
more » ... of FEOS in a Widom equation of state in the critical region. The method has been tested on the example of FEOS of R218. The area of applicability of FEOS is 0 < ρ/ρc < 3.2 in the density and 133 < T < 440 K in the temperature. We have compared FEOS with some equations of state and discussed the results.
doi:10.1088/1742-6596/946/1/012118 fatcat:nptm66zvtjd4ddtt2yr3mis5gm
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I V Kudryavtseva, V A Rykov, S V Rykov, E E Ustyuzhanin. "A new variant of a scaling hypothesis and a fundamental equation of state based on it." Journal of Physics, Conference Series (2018) 012118