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Hydrogen Evolution Reaction (HER) is an attractive technology for chemical conversion of energy. Replacement of platinum with inexpensive and stable electrocatalysts remains a major bottleneck hampering large-scale hydrogen production by using clean and renewable energy sources. Here, we report electrocatalytically active and ultra-stable Polymer-Derived Ceramics towards HER. We successfully prepared ultrathin silicon and carbon (Si-C) based ceramic systems supported on electrically conductingdoi:10.1038/s41598-020-78558-x pmid:33319809 fatcat:bfaghftca5hsboiuavts5q6cea