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Synthesis of Quinoline Derivatives Containing Lactone Structure Promoted by Radical Cation Salt
Using aniline derivatives containing lactone structure and styrenes as the starting materials, a series of lactone substituted quinolines were constructed efficiently by oxidative Povarov reaction, promoted by radical cation salt. This reaction provides a new method to achieve the construction of functionalized quinoline skeletons. The mechanistic study reveales that the oxidation of the saturated C-H bond is mediated by free radical intermediate.doi:10.6023/cjoc201804012 fatcat:zqo443xinndv5ixkoftbi5mcbi