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The hydrogen evolution reaction (HER) is the cathodic process in many important electrochemical technologies. According to the Brewer intermetallyc bonding theory, molybdenum and tungsten were alloyed with nickel (hypo-hyper-d- electronic transition metal) in order to increase the intrinsic catalytic activity for HER. Cobalt was also combined with nickel to evaluate the effect of this metal in the intrinsic catalytic activity. In all the cases, electrodeposition at very high current densitiesdoi:10.3303/CET1332145 doaj:a3444fc4128a47b69516ab5791218819 fatcat:q2y4j6iwjjgp3gkyacgviw4uqa