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Vibrational enhancement of electron emission in CO (a3Π) quenching at a clean metal surface
2013
Physical Chemistry, Chemical Physics - PCCP
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We have combined a Stark decelerator with a molecular beam-surface scattering setup to accurately measure the absolute electron emission yield, c, of CO (a 3 P) quenching at a Au(111) surface with quantum state resolution. We clearly observe an enhanced probability of electron emission when scattering vibrationally excited states of CO from the surface.
doi:10.1039/c3cp52468j
pmid:23925709
fatcat:bwtqg5xxebenvkwykg3smhwtqa