Cellulose films regenerated from aqueous alkali-urea solution possess different properties depending on coagulation conditions. However, the correlation between coagulant species and properties of regenerated cellulose (RC) films has not been clarified yet. In this study, RC films were prepared from cellulose nanofiber (CNF) and microcrystalline cellulose (MCC) under several coagulation conditions. Cellulose dissolved in aqueous LiOH/urea solution was regenerated using various solvents at

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... t temperature to investigate the effects of their polarity on the properties of RC film. The crystal structure, mechanical properties, and surface morphology of prepared RC films were analyzed using X-ray diffraction (XRD), tensile tester, and atomic probe microscopy (AFM), respectively. It is revealed that the preferential orientation of (110) and (020) crystal planes, which are formed by intra- and inter-hydrogen bonding in cellulose crystal regions, changed depending on coagulant species. Furthermore, we found out that tensile strength, elongation at break, and crystal structure properties of RC film strongly correlate to the dielectric constant of solvents used for coagulation process. This work, therefore, would be able to provide an indicator to control the properties of RC film depending on its application and to develop the detailed research on controlling the crystal structure of cellulose.