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A method is described for the chiral construction of 3-lactams (and consequently other derivatives that use /3-lactams as starting materials, e.g. amino sugars) in a versatile, high yielding, and predictable manner. We have postulated a variation on the mechanism of the Staudinger reaction which explains the origins of the chiral induction in the reaction and using computational methods have been able to achieve a theoretical justification for our experimental observations. Research intodoi:10.1351/pac198759030485 fatcat:v6wqurymk5g7zi7u27d4tuvli4